• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a transparent sheet comprising a relief texture on a first of its main faces, such that if n is the refractive index of the material comprising the texture, Pm is the average slope in degree of the textured face, Y ( q) is the percentage of the textured surface of slope greater than q / (n-1) in degree, then we have the two cumulative conditions Y (q)> 3% + f (q)% .Pm. (n-1) ) and Y (q)> 10%, with f (q) = 24- (3.q) and q = 2 or 3.
    公开号:FR3035398A1
    申请号:FR1554131
    申请日:2015-05-07
    公开日:2016-10-28
    发明作者:Michele Schiavoni；Mathieu Berard；Emmanuel Mimoun；Simon Mazoyer
    申请人:Saint Gobain Glass France SAS；
    IPC主号:
    专利说明:

    [0001] The invention relates to the field of glazing with high transparency and diffusing, in particular for horticultural greenhouses.
    [0002] At present, non-surface textured flat glazings are mainly used for the greenhouse application for horticulture. In recent years, textured glazings whose texture is obtained by rolling have appeared for this application. These textured lenses diffuse light, which has a positive impact on horticultural production. Indeed, the diffusion effect avoids the hot spots on the plants and allows a better penetration of the light in all the zones of the greenhouse and makes it possible to obtain a more homogeneous lighting. On the other hand, these glasses have a lower transmission compared to the same non-textured glass, which has a negative impact on horticultural production. The strong transmission sought for these glazings is the so-called hemispheric transmission (TLH, sometimes referred to as THEm), that is to say the transmission averaged over several angles of incidence. For each angle of incidence, we measure all the light intensity through the glazing regardless of the angle of emergence. A glazing for greenhouses preferably has a strong TLH and a blur (as determined by the Haze value, called H) high. Haze is the ratio between the diffuse transmission and the total transmission of the glazing. The hemispherical transmission is an essential feature of this type of glazing and it is generally not desired that the glazing lose more than 5% and preferably not more than 3% TLH because of its diffusing texture compared to a flat glass non-textured of the same nature and same surface mass. A gain or loss of 1% TLH is already very sensitive. For Haze, a significant variation is rather of the order of 10%. Photovoltaic glazings, such as those marketed under the Albarino-S and Albarino-T brands by Saint-Gobain, make it possible to substantially obtain this type of behavior. However, for the Albarino-S, the H is high but the TLH is degraded compared to a flat glass of the same kind, and for the Albarino-T, the TLH remains at a high level close to that of a glass smooth of the same kind, but the H is too weak. Although they represent a certain improvement over non-textured glazing, these windows are not ideal. The W003046617 teaches a textured plate by pyramids for photovoltaic use. The Albarino-P marketed by Saint-Gobain has a structure of this type. The faces of its pyramids have a slope approaching 45 °, but due to roundings involuntarily achieved in practice, the texture of this glazing actually has an average slope of about 30 ° relative to the general plane of the glazing. If such a texture leads to a high H, the TLH is not sufficient. The invention provides a better compromise of these two properties TLH and H compared to known textured glazings. The invention firstly relates to a transparent sheet comprising a texture in relief on a first of its main faces, such that if n is the refractive index of the material comprising the texture, 13, is the average slope in degree of the textured face, Y (q) is the percentage of the textured surface of slope greater than q / (n-1) in degree, then we have the two cumulative conditions on Y (q): Y (q)> 3% + f (q) (:) 0 .13 ,. (n-1) and Y (q)> 10% with f (q) = 24- (3.q) and q = 2 or 3. Preferably, Y (q)> 5`) / o + f (q )%. P,. (n-1). More preferably, Y (q)> 10% + f (q) /0.13, (n-1). Preferably f (q) = 27- (3.q) and even f (q) = 30- (3.q).
    [0003] In particular, one of the following eight combinations is particularly suitable: - Y (q)> 5`) / o + f (q)% .P,. (N-1) with f (q) = 27- (3 q) and q = 2; or - Y (q)> 5`) / o + f (q)%, P, (n-1) with f (q) = 27- (3.q) and q = 3; or - Y (q)> 5`) / o + f (q)% .P,. (n-1) with f (q) = 30- (3.q) and q = 2; or 25 - Y (q)> 5`) / o + f (q)%, P, (n-1) with f (q) = 30- (3q) and q = 3; or - Y (q)> 10% + f (q) / .P,. (n-1) with f (q) = 27- (3q) and q = 2; or - Y (q)> 10% + f (q) / .P,. (n-1) with f (q) = 27- (3q) and q = 3; or - Y (q)> 10% + f (q) / .P,. (n-1) with f (q) = 30- (3q) and q = 2; or - Y (q)> 10% + f (q) / .P,. (n-1) with f (q) = 30- (3.q) and q = 3.
    [0004] In the context of the present application and in particular in the examples, TLH and Haze are measured according to the methods detailed in Procedes IS on light in Horticultural Systems, Eds S. Hemming and E. Heuvelink, Acta Hort.956. , ISHS 2012 ". In this document, mention is made of a Haze measured at 1.5 °. In the field of transparent materials, the Haze is often measured at 2.5 °.
    [0005] 3035398 3 A standard has not yet been fully established in the greenhouse sector for horticulture, although the Haze 1.5 degree is now more used. According to the invention, an f (q) is introduced to take account of these two ways of measuring the haze. To maximize a Haze at 1.50 while keeping a very good compromise with 5 TLH, we take q = 2 whereas to maximize a Haze at 2.5 ° while keeping a very good compromise with the TLH, we take q = 3. According to the invention, a glazing unit having a slope distribution comprising relatively few areas with a very small slope and few areas with a large slope and whose slope distribution is close to q / (n-1) in ° is used with q = 2 10 or 3, that is to say close to 4 ° for q = 2 and close to 6 ° for q = 3 for glass of index 1.5. Thanks to this geometry, a much better combination of values TLH and H is obtained. The relief texture can be produced in a material of the organic or inorganic glass type. In particular, it may be a mineral glass comprising at least 40% by weight of 5iO 2. The refractive index of the material comprising the texture is generally in the range of 1.4 to 1.65 at 587 nm. The sheet is not very absorbent in the spectral range of photosynthesis (400-700 nm) and it is the same for any material included in the sheet.
    [0006] The absorption of the sheet according to the invention in this spectral range is less than 2% and preferably less than 1% and even less than 0.5%. The absorption is obtained by the measurement of the transmission and reflection in normal incidence and by the relation Absorption (`) / 0) = 100% - transmission (`) / 0) - reflection (%). The transmission and reflection measurements (global and measured with an integrating sphere) are made using a spectrophotometer and correspond to an average of the transmission and reflection values for the wavelengths. from the 400-700 nm domain. The slope at a point on the surface of a sheet corresponds to the angle formed between the tangent plane at this point and the general plane of the sheet. The measurement of the slope at a point is made from the measurement of the variation of height in the vicinity of this point and with respect to the general plane of the sheet. The skilled person knows the devices capable of performing these measurements of height. The measurement of the average slope P of the surface is determined from the measurement of slopes at points distributed over a square mesh with a period of 20 μm. The average of the slope of all these points is then calculated. Preferably, the texture comprises relatively large patterns because it allows better control of the slopes actually created by rolling. Indeed, it is in practice very difficult to obtain by rolling a texture with controlled slopes when the period of the patterns is less than 1 mm, especially in a mineral glass. The rolling process necessarily produces undesired roundings and these rounds with uncontrolled slopes occupy all the more surface area as the basic pattern is of small size. By enlarging the pattern, the same rounding takes up a smaller fraction of the total pattern period and therefore has a smaller impact. To obtain by rolling a texture close to that desired, patterns having a size of at least 1 mm and preferably at least 1.5 mm and preferably at least 2 mm and even preferably at least 2.5 mm (by size is meant the diameter of the smallest circle containing the pattern). Preferably, the patterns have a size of at most 8 mm. Preferably the patterns are joined. Remember that the Rsm (mean or mean period) of a profile (that is to say along a line segment) of a surface is defined by the relation: vi = n S S2 + + S i = 1 where Si is the distance between two zero crossings (center line) and amounts, where n + 1 is the number of zero crossings in the profile considered. This parameter Rsm is representative of the distance between peaks, that is to say the pitch of the texture parallel to the general plane of the sheet. The values of Rsm are given after using Gaussian filters with cuts (or base length, cut-off in English) at 25 μm and 8 mm (deletion of periods less than 25 μm and greater than 8 mm). The Rsm measurements are made over a distance of at least 40 mm. For any point on the textured surface, the Rsm about said point corresponds to the arithmetic mean of the Rsm 1 Si 3035398 5 for 10 star starting profiles from the point considered. For the calculation of the Rsm around a point, values greater than or equal to 40 mm are removed. This avoids taking into account profiles in particular texture guidelines such as parallel prisms or straight lines between aligned pyramids (value of Rs, infinite or non-calculable). Rs, mean of a textured surface, are also defined by calculating the arithmetic mean of the Rs, around a point, the points being chosen on a square grid with a pitch of 5 cm. Preferably, the average Rs of the textured surface is in the range of 1 mm to 8 mm and preferably in the range of 1.5 to 8 mm and even in the range of 2 mm to 8 mm. and even in the range of 2.5 mm to 8 mm. More preferably, the Rs around any point on the textured surface is in the range of 1 mm to 8 mm and preferably in the range of 1.5 to 8 mm and even in the range from 2 mm to 8 mm and even in the range of 2.5 mm to 8 mm. The slopes made on a mineral glass by hot rolling, generally in a temperature range of 800 to 1300 ° C, decrease slightly during forming. Thus, if a mean slope of value Pm is aimed at the level of the glass sheet, a printing roll 20 is preferably used whose patterns have an average slope of at least P + 0.5 °, or even by at least Pm + 10. The larger the texture patterns (Rs, higher average), the closer the actual printed texture is to that of the roll and the less need to make a correction to the roll patterns. Thus, for an average Rs of between 1 and 1.5 mm, the average slope of the roll texture can be increased by 0.5 ° to 10 ° with respect to the average slope of the desired texture. For an average Rs of between 1.5 and 2 mm, the average slope of the roll texture can be increased by 0.5 ° to 8 ° with respect to the average slope of the desired texture. For an average Rs of between 2 and 2.5 mm, the average slope of the roll texture can be increased by 0.5 ° to 6 ° with respect to the average slope of the desired texture. For an average Rs greater than 2.5 mm, the average slope of the roll texture can be increased by 0.5 ° to 50 relative to the average slope of the desired texture. The patterns of the texture may be parallel linear patterns such as parallel prisms or patterns that may fit in a circle such as cones or pyramids. The invention is useful for acting as glazing allowing the light of greenhouses for horticulture, as well as for other applications requiring a strong 5 TLH and a H fort as a veranda, a lobby, a public space . According to the invention, the two main faces of the sheet may have a texture. In this case, if the texture of one of the two faces is not according to the invention, then, preferably, the texture according to the invention is that of the two faces whose average slope is the strongest. The less steep average slope face is preferably such that 13, 2. (n-1) is less than 3 ° and even less than 2 °, 13, and n 'being the average slope and the refractive index of the material comprising the texture of this face with a lower average slope. The invention also relates to a sheet with 13, (n-1) greater than Pny. (N-1), 13, and 13, 'representing the mean slope respectively of the first and second major faces and n and n 'being the index of refraction of the material comprising the texture respectively of the first and second main face. Preferably, the texture of the second major face has a mean slope such that 13, 2. (n-1) is less than 3 ° and even less than 2 °. Preferably, if Y '(q) is the percentage of the textured surface having a slope greater than q / (n-1) in degree of the second major face, then the relationship Y' (q)> 3% + f (q) /0.13, '. (n-1) with f (q) = 24- (3.q) and q being 2 for both for Y (q) and for Y' (q), or q being 3 at a time for Y (q) and for Y '(q).
    [0007] In particular, both sides of the sheet may be according to the invention. An anti-reflective effect can be obtained on one or both sides of the sheet, and in particular on the textured face. This antireflection effect can be obtained by the deposition of a layer or of several layers forming a stack, by etching or any other suitable technique. The antireflection effect is chosen to be effective at 400-700 nm wavelengths. An anti-reflection coating (anti-reflection layer or anti-reflection layer stack) generally has a thickness in the range of 10 to 500 nm. The sheet may be made of a totally monolithic material. The sheet may also be made of a monolithic material on which is optionally affixed an anti-reflection layer or a stack of anti-reflective layers on one of its faces or on both sides. However, the texture may be made of a first relatively thin material comprising the texture and associated in the sheet with a second material giving rigidity to the entire sheet. It is appropriate for this first material to be present in a minimum thickness enabling the relief patterns to be produced. Preferably, the difference in the refractive indices of these two materials does not exceed 0.2 and more preferably does not exceed 0.1. In this case, it is a combination of several materials when the texture is produced by embossing a sol-gel layer deposited on a transparent sheet, in particular glass. Thus, the texture can be made of a first material attached to a sheet of a second material. The sheet may also include more than two materials. Preferably, two materials juxtaposed in the sheet have refractive indices the difference of which does not exceed 0.2 and preferably does not exceed 0.1. This preference concerns the juxtaposition within the sheet of materials both present at more than 500 nm from the surface of the sheet, the surface of the sheet being in contact with the ambient air. A material present at more than 500 nm from the surface of the sheet may also be present on the surface of the sheet, its thickness then being greater than 500 nm. The presence of a material at more than 500 nm from the surface is determined orthogonally with respect to the actual surface, which follows the texture, and not with respect to the general plane of the sheet. refraction, does not therefore concern an antireflection coating (antireflection layer or antireflection stack), which is in contact with the ambient air and is generally made of materials with refractive indices rather far from that on which it is deposited, and thickness less than 500 nm. An anti-reflective layer or antireflection stack are thin coatings that do not alter the relief texture on which they are applied. They follow the relief on the surface. Therefore, it can be said that an antireflection surface coating (layer or stack of layers) in contact with the ambient air is not the material comprising the texture according to the invention. The material comprising the texture according to the invention is of sufficient thickness to confer on itself the texture on the surface. It may be coated with an antireflection coating (antireflection layer or antireflection stack) but this coating follows the surface relief given by the material comprising the texture. Thus, the material comprising the texture according to the invention is of sufficient thickness to constitute more than 90% and preferably more than 95% by volume of the material between two planes parallel to the general plane of the sheet and one of which passes through the outermost point of the texture in contact with the ambient air and the other passes through the innermost point of the texture in contact with the ambient air. In practice, it is in this material that the texture is printed by a tool comprising the same inverted relief or by chemical etching. The material comprising the texture is in thickness greater than 5 μm in a direction orthogonal to the actual surface (which follows the surface texture), and in thickness greater than 5 μm in a direction orthogonal to the general plane of the sheet. If the texture according to the invention does not comprise at its anti-reflective layer or stacking surface, then the material comprising the texture according to the invention is in contact with the ambient air. If the texture according to the invention comprises on its surface a layer or an anti-reflection stack, then it is the layer or the stack which is in contact with the ambient air. The texture in a monolithic material, especially glass, can generally be achieved by embossing or rolling with at least one textured roll, or by acid etching. The resulting textured glass sheet may be coated with an antireflection coating. If the sheet according to the invention comprises a glass sheet, it is preferably thermally toughened. To do this, and for the case where an antireflection coating is to be applied thereto, it is possible in particular to proceed as follows: rolling of glass to its softening temperature by at least one textured roll leading to a textured glass sheet, then cooling, then, - application on one or both sides of the textured sheet of one or more precursor sol-gel layer (s) of an anti-reflection coating, then - heating the coated textured sheet, followed thermal quenching cooling; the heating serves both to bring the glass to the temperature for quenching cooling, but also to the baking of the sol-gel coating.
    [0008] FIG. 1 shows the textured face of a glass sheet according to the invention, obtained by rolling and according to example 1. The texture of a main face comprises pyramids with irregular base in hollow and contiguous. The degree of gray reflects the depth of the points on the surface, the darkest areas being the deepest. In each of Figures 1 to 3, the lightest points are at the same height and the darkest points are at the same height. The depth of the patterns is the difference in height orthogonal to the general plane of the plate between the lightest points and the darkest points. FIG. 2 shows the textured face of a glass sheet according to the invention, obtained by rolling and according to Example 2. The texture of a main face comprises pyramids with irregular bases in hollow and joined. The pyramids are smaller than in the case of Figure 1, so that involuntarily rounded areas are larger. These rounded areas do not necessarily have the desired slope.
    [0009] Figure 3 shows the textured face of a glass sheet according to the invention, obtained by rolling and according to Example 3. The texture of a main face comprises pyramids with irregular base recessed and contiguous. The pyramids are smaller than in the case of Figures 1 and 2, so that involuntarily rounded areas are larger. These rounded areas do not necessarily have the desired slope. Figure 4 shows the most heavily textured face of a Albarino leaf viewed from above in a) and side view in b). Of course the reasons in b) are not to scale. We show here that the patterns are bumps regularly distributed on the surface.
    [0010] FIG. 5 illustrates the impact of a change in the size of pyramidal patterns (and therefore a change in Rsm). The two textures in a) and b) have the same rounding with the same radii of curvature at the vertices and hollows of the patterns. This is practically achieved by rolling the glass with a textured roll having pyramids at its surface without rounding at the vertices and troughs of the patterns. The larger texture in a) has a texture closer to the ideal texture since it has larger areas of adapted slope. FIG. 6 shows in the case of q = 2 how the invention differs from the prior art by the line Y = X, with X = 3% + 18% .P,. (N-1) because f (q 2. The points in this figure correspond to the examples in Table 1. The field of the invention is above this line and above a horizontal line Y = 10%. . Figure 7 shows in the case of q = 3 how the invention is distinguished from the prior art by the line Y = X, with X = 3% r (n-1) because f (q) = 15% for q = 3. The points in this figure correspond to the examples of Table 2. The field of the invention is above this line and above a horizontal line Y = 10%. Figure 8 shows a sheet 70 according to the invention in section in its slice. The textures and thicknesses are not to scale. This sheet 70 is made of a silicosodocalcic mineral glass obtained by rolling between two rollers, one of which was textured. The upper face 71 of the sheet has a texture according to the invention with juxtaposed pyramidal patterns. An anti-reflection layer 72 has been deposited on the textured face of the monolithic substrate. The second face 73 of the sheet is flat, without any particular texture. The material comprising the texture is the material 70 and not the material of the layer 72. Figure 9 shows a sheet 80 according to the invention in section in its section. The textures and thicknesses are not to scale. This sheet 80 is made of a silicosodocalcic mineral glass obtained by rolling between two rollers, both textured. The upper face 81 of the sheet has a texture according to the invention with juxtaposed pyramidal patterns. The second face 82 of the sheet has a texture (according to the invention or not) with juxtaposed pyramidal patterns, the average slope on the second face 82 being less than the average slope on the first face 81. This sheet is totally monolithic.
    [0011] Its material includes the textures of each face. Figure 10 shows a sheet 90 according to the invention in section in its section. The textures and thicknesses are not to scale. A substrate sheet 91 of silicosodocalcic glass gives its rigidity to the assembly. This substrate sheet 91 is a mineral sheet obtained by hot rolling between two textured rollers. The two faces 92 and 93 of this substrate sheet 91 are consequently textured. The substrate sheet 91 may be considered to be an AlbarinoT leaf. Above the face 92 of the substrate sheet 91 has been produced a texture 94 according to the invention by embossing a sol-gel layer. The sol-gel material 95 and the material of the substrate sheet 91 have near refractive indices, the difference in their refractive indices not exceeding 0.1. Here, the material comprising the texture according to the invention is the sol-gel material 95. In the examples which follow, the sheets had a thickness of 4 mm. The average slope and the slope percent greater than q / (n-1) were varied in degrees, with q being 2 for Examples 1 to 9 and 3 for Examples 10 to 17. The results are reported. respectively in Tables 2 and 3. The Haze values are measured at 1.5 ° for Examples 1 to 9 and at 2.5 ° for Examples 10 to 18. The TLH values are given in relation to flat glass of the same nature and of the same surface mass. This is therefore the loss of TLH in%, denoted ATLH 10 with respect to flat glass. Indeed, flat glass necessarily has a higher TLH value than textured glasses in the same material. We try to make ATLH as small as possible. EXAMPLES 1 to 9 For Examples 1 to 4, glass sheets having a textured main face whose texture is a repetition of unevenly-based pyramidal patterns in hollow of different sizes as reflected by the value of Rsm are made by rolling. The glazings of Examples 5 to 9 are commercial and comparative. The textures obtained for Examples 1 to 3 are those shown in Figures 1 to 3 respectively, the depth being the difference in height between the lightest and darkest points of these figures. From Figure 1 to Figure 3, there is an increase in the proportion of rounded areas that do not correspond exactly to those desired. The texture of Example 4 is similar in plan view to that of Figure 2, the difference being in depth. Examples 5 to 9 correspond to characteristics measured on textured glasses marketed under the marks appearing in column 1 of the table. For all the examples, the refractive index of the mineral glass used was 1.52. In the table, X represents 3% + 18% .P,. (N-1) because f (q) = 18% for q = 2. Example No. depth (1-inn) Average Rsm (mm) Pm (°) X (%) Y (%) Haze ATLH (% at 1.5 °) (%) 1 174 3.6 4 40.44 100 100% 2 2 100 1.8 3.8 38.55 61 75% 1.9 3 100 1.3 4.9 48.9 70 79% 2.5 4 80 1.8 3 31.08 50 60% 1.5 5 (Albarino-S) - 0.8 9.5 91.92 80 85% 5 6 (Albarino-T) - 0.8 2 21.72 15 20% 1 7 (Albarino-P) - 2.5 30 283.8 90 95% 15 8 (Arena C) - 5 49.8 40 50% 2.5 9 (Vetrasol) - 6 59.16 48 56% 3 Table 1 It can be seen that for Example 5 the Haze value is good but that the TLH is extremely reduced. With respect to Example 6, the Haze value is extremely low. Examples 7 to 9 do not offer very good property compromises. Examples 1 to 4 provide excellent property compromises in 10 Haze and TLH. This corresponds to the fact that for these examples, Y> X. EXAMPLES 10-17 For Examples 10-12, glass sheets having a textured main face whose texture is a repetition of unevenly-based pyramid-shaped patterns of different sizes as reflected by the value of Rsm are made by rolling. The windows of Examples 13 to 17 are commercial and comparative. The textures obtained for examples 10 to 12 are those shown respectively in FIGS. 1 to 3, the depth being the difference in height between the lightest and darkest points of these figures. These 20 textures are different from those of the examples. 1 to 3 by the depth which is here chosen deeper. Examples 13 to 17 correspond to characteristics measured on textured glasses marketed under the marks appearing in column 1 of Table 2. For all the examples, the refractive index of the mineral glass used was 1.52. In Table 2, X represents 3Y0 + 15% .P,. (N-1) because 25 f (q) = 15% for q = 3. Example No. depth (1-inn) Average Rsnn (mm) Pm (°) X (%) Y (%) Haze ATLH (% at 2.5 °) (%) 10 260 3.6 6 49.8 100 100% 3 11 150 1.8 5.7 47.5 61 70% 2.9 12 150 1.3 7.4 60.7 70 75% 3.7 13 (Albarino-S) - 0.8 9.5 77.1 65 75% 5 14 (Albarino-T) - 0 , 8 2 18.6 8 10% 1 15 (Albarino-P) - 2.5 30 237.0 88 92% 15 16 (Arena C) - 5 42.0 25 30% 2.5 17 (Vetrasol) - 6 49.8 30 32% 3 Table 2 It can be seen that for example 13 the Haze value is good but that the TLH is extremely reduced. With respect to Example 14, the Haze value is extremely low. Examples 13 to 17 do not offer very good property compromises. Examples 10 to 12 provide excellent property compromises in Haze and TLH. This corresponds to the fact that for these examples, Y> X.
    权利要求:
    Claims (21)
    [0001]
    REVENDICATIONS1. A transparent sheet comprising a texture in relief on a first of its main faces, such that if n is the refractive index of the material comprising the texture, 13 is the average slope in degree of the textured face, Y (q) is the percentage of the textured surface of slope greater than q / (n-1) in degree, then we have the two cumulative conditions Y (q)> 3% + f (q) /0.13,. (n-1) and Y ( q)> 10% with f (q) = 24- (3.q) and q = 2 or 3.
    [0002]
    2. Sheet according to the preceding claim, characterized in that Y (q)> 5% + f (q) /0.13, (n-1).
    [0003]
    3. Sheet according to the preceding claim, characterized in that Y (q)> 10% + f (q) /0.13, (n-1).
    [0004]
    4. Sheet according to one of the preceding claims p, characterized in that f (q) = 27- (3.q) or even f (q) = 30- (3.q).
    [0005]
    5. Sheet according to one of the preceding claims, characterized in that q = 2.
    [0006]
    6. Sheet according to one of claims 1 to 4, characterized in that q = 3.
    [0007]
    7. Sheet according to claim 1, characterized in that one of the following combinations: Y (q)> 5`) / o + f (q)% .P,. (N-1) with f (q) = 27- (3.q) and q = 2; or - Y (q)> 5`) / o + f (q)%, P, (n-1) with f (q) = 27- (3.q) and q = 3; or - Y (q)> 5`) / o + f (q)% .P,. (n-1) with f (q) = 30- (3.q) and q = 2; or - Y (q)> 5`) / o + f (q)% .P,. (n-1) with f (q) = 30- (3.q) and q = 3; or - Y (q)> 10`) / 0 + f (q)% .P,. (n-1) with f (q) = 27- (3.q) and q = 2; or - Y (q)> 10`) / 0 + f (q)%, P, (n-1) with f (q) = 27- (3.q) and q = 3; or - Y (q)> 10`) / 0 + f (q)%, P, (n-1) with f (q) = 30- (3.q) and q = 2; or - Y (q)> 10`) / 0 + f (q)%, P, (n-1) with f (q) = 30- (3.q) and q = 3.
    [0008]
    8. Sheet according to one of the preceding claims, characterized in that the refractive index of the material comprising the texture is in the range of 1.4 to 1.65 to 587nm. 3035398 15
    [0009]
    9. Sheet according to one of the preceding claims, characterized in that the absorption of the sheet in the spectral range in the range of 400 to 700 nm is less than 2% and preferably less than 1% and even lower. at 0.5%. 5
    [0010]
    10. Sheet according to one of the preceding claims, characterized in that the material comprising the texture is mineral glass.
    [0011]
    11. Sheet according to one of the preceding claims, characterized in that the roughness of the textured surface is such that the average Rsm is greater than 1 mm and preferably greater than 1.5 mm and even greater than 2 mm, and less than 8 mm.
    [0012]
    12. Sheet according to one of the preceding claims, characterized in that the texture comprises contiguous patterns of size in the range of 2 to 8 mm.
    [0013]
    13. Sheet according to one of the preceding claims, characterized in that its second main face also has a texture, such that Pm. (N-1) is greater than Pm '. (N-1), Pm' representing the average slope of the second main face and n 'being the refractive index of the material comprising the texture of the second main face.
    [0014]
    14. Sheet according to the preceding claim, characterized in that the texture of the second main face at a mean slope such that Pm'.2. (N'-1) is less than 3 ° and even less than 2 °.
    [0015]
    15. Sheet according to one of the two preceding claims, characterized in that, if Y '(q) is the percentage of the textured surface of slope greater than q / (n-1) in degree of the second main face, then we have the relation Y '(q)> 3% ± f (q) 0 / 0.-rm ,. (n-1) with f (q) = 24- (3.q) and q being 2 for both for Y (q) and for Y '(q), where q is 3 at a time for Y (q ) and for Y '(q). 30
    [0016]
    16. Sheet according to one of the preceding claims, characterized in that it comprises an anti-reflective coating on one or both sides.
    [0017]
    Horticultural greenhouse equipped with a sheet of one of the preceding claims. 3035398 16
    [0018]
    18. A method of manufacturing a sheet of one of the preceding claims of sheet by rolling with a textured printer roll.
    [0019]
    19. Method according to the preceding claim, characterized in that the textured printer roll supports patterns having an average slope greater than the average slope of the first major face of the sheet obtained.
    [0020]
    20. Method according to the preceding claim, characterized in that the textured printer roll supports patterns having an average slope greater than at least 0.5 ° to the average slope of the first major face of the sheet obtained.
    [0021]
    21. Method according to the preceding claim, characterized in that the textured printer roll supports patterns having an average slope greater than at least 1 ° to the average slope of the first major face of the sheet obtained. 15
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    同族专利:
    公开号 | 公开日
    FR3035397A1|2016-10-28|
    EP3286149B1|2019-01-02|
    WO2016170261A1|2016-10-27|
    US10246363B2|2019-04-02|
    DK3286149T3|2019-04-23|
    RU2696907C2|2019-08-07|
    UA122410C2|2020-11-10|
    US20180141845A1|2018-05-24|
    RU2696907C9|2020-01-28|
    CN107466202A|2017-12-12|
    PT3286149T|2019-04-23|
    RU2017135226A|2019-04-08|
    RU2017135226A3|2019-05-30|
    EP3286149A1|2018-02-28|
    FR3035398B1|2017-06-02|
    PL3286149T3|2019-07-31|
    CA2981682A1|2016-10-27|
    JP2018517649A|2018-07-05|
    CN107466202B|2020-12-01|
    JP6793130B2|2020-12-02|
    ES2717824T3|2019-06-25|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CH693771A5|2001-02-15|2004-01-30|Interfloat Corp|Glass, in particular for use in solar applications.|
    EP1449017B1|2001-11-28|2007-08-29|Saint-Gobain Glass France|Textured transparent plate with high light transmission|
    WO2010084290A1|2009-01-23|2010-07-29|Saint-Gobain Glass France|Substrate en verre transparent glass substrate and method for producing such a substrate|
    WO2011006957A2|2009-07-16|2011-01-20|Saint-Gobain Glass France|Textured transparent plate and method for manufacturing such a plate|
    WO2014111662A1|2013-01-21|2014-07-24|Saint-Gobain Glass France|Textured glass substrate for a building|
    WO2014131610A1|2013-02-27|2014-09-04|Agc Glass Europe|Textured glass sheet having straight patterns|
    WO2015032618A1|2013-09-03|2015-03-12|Agc Glass Europe|Textured glass sheet with rectilinear features|
    US653238A|1899-09-25|1900-07-10|Edward Walsh Jr|Means for forming sheet-glass of the prismatic type.|
    SU67217A1|1945-12-01|1946-10-31|И.К. Матвеев|Method for continuous production of wavy reinforced glass|
    SU899502A1|1978-12-26|1982-01-23|Центральный научно-исследовательский и проектно-экспериментальный институт промышленных зданий и сооружений|Apparatus for molding profiled glass products|
    SU854896A1|1979-06-08|1981-08-15|Производственное Объединение "Техэнергохимпром"|Device for making articles from thermolastic material|
    DE50101048D1|2001-02-15|2004-01-08|Interfloat Corp|GLASS|
    CN100501458C|2003-10-27|2009-06-17|松下电器产业株式会社|Light quantity distribution control element and optical apparatus using the same|
    NL1025191C2|2004-01-08|2005-07-11|Agrotechnology And Food Innova|Cover for an object using a solar radiation.|
    FR2870007B1|2004-05-10|2006-07-14|Saint Gobain|TRANSPARENT SHEET TEXTURED WITH INCLINED PYRAMIDAL PATTERNS|
    CN201084734Y|2007-08-16|2008-07-09|李彪|An ultra-white embossed glass with novel pattern|
    NL2002432C2|2009-01-20|2010-07-21|Omt Solutions Beheer B V|Diffusing device for diffusing light, and safety-glass panel, light source and greenhouse comprising diffusing device.|
    BE1020735A3|2012-05-29|2014-04-01|Agc Glass Europe|VERTICAL TEXTURE SUBSTRATE WITH IMPROVED OPTICAL PROPERTIES FOR OPTOELECTRONIC DEVICE.|
    CN203141916U|2013-01-24|2013-08-21|河南裕华新材料股份有限公司|High-transmitting low-scattering glass|
    CN103258887B|2013-04-28|2016-08-17|中航三鑫太阳能光电玻璃有限公司|A kind of energy ultrawhite figured glass|DE102016212225A1|2016-07-05|2018-01-11|Siemens Healthcare Gmbh|Method for producing a sheet-like insulating layer for use in a gradient coil, insulation layer produced according to the method, method for producing a gradient coil and gradient coil produced according to the method|
    FR3071242B1|2017-09-15|2022-02-04|Saint Gobain|TRANSPARENT TEXTURED SUBSTRATE, PARTICULARLY FOR GREENHOUSES|
    FR3085372B1|2018-08-31|2020-08-28|Saint Gobain|TEXTURED GLASS AND GREENHOUSE INSULATION|
    FR3088634A1|2018-11-16|2020-05-22|Saint-Gobain Glass France|LUMINESCENT TEXTURE GLASS FOR GREENHOUSES|
    FR3107056A1|2020-02-06|2021-08-13|Saint-Gobain Glass France|LAYERED GLAZING AND ITS MANUFACTURING|
    WO2022043186A1|2020-08-28|2022-03-03|Agc Glass Europe|Improved greenhouse glazing|
    法律状态:
    2016-04-20| PLFP| Fee payment|Year of fee payment: 2 |
    2016-10-28| PLSC| Search report ready|Effective date: 20161028 |
    2017-04-21| PLFP| Fee payment|Year of fee payment: 3 |
    2018-04-25| PLFP| Fee payment|Year of fee payment: 4 |
    2019-05-22| PLFP| Fee payment|Year of fee payment: 5 |
    2020-05-28| PLFP| Fee payment|Year of fee payment: 6 |
    2021-05-31| PLFP| Fee payment|Year of fee payment: 7 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1553648A|FR3035397A1|2015-04-23|2015-04-23|TEXTURE GLASS FOR GREENHOUSE|DK16722290.0T| DK3286149T3|2015-04-23|2016-04-19|TEXTURED GLASS FOR GREENHOUSE|
    ES16722290T| ES2717824T3|2015-04-23|2016-04-19|Textured glass for greenhouses and associated manufacturing process|
    PT16722290T| PT3286149T|2015-04-23|2016-04-19|Textured glass for greenhouses|
    US15/568,261| US10246363B2|2015-04-23|2016-04-19|Textured glass for greenhouses|
    CA2981682A| CA2981682A1|2015-04-23|2016-04-19|Textured glass for greenhouses|
    RU2017135226A| RU2696907C9|2015-04-23|2016-04-19|Textured glass for greenhouses|
    PCT/FR2016/050903| WO2016170261A1|2015-04-23|2016-04-19|Textured glass for greenhouses|
    JP2017555353A| JP6793130B2|2015-04-23|2016-04-19|Textured glass for greenhouses|
    EP16722290.0A| EP3286149B1|2015-04-23|2016-04-19|Textured glass for greenhouses and associated producing process|
    PL16722290T| PL3286149T3|2015-04-23|2016-04-19|Textured glass for greenhouses and associated producing process|
    UAA201711434A| UA122410C2|2015-04-23|2016-04-19|Textured glass for greenhouses|
    CN201680023455.2A| CN107466202B|2015-04-23|2016-04-19|Textured glass for greenhouse|
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